S → aS | aSbS | (empty) where the alphabet is {a,b}
in other words, the set of strings where any prefix has at least as many 'a's as 'b's.
A grammar that can do this unambiguously is:
$S \to aS \mid A S \mid \epsilon$ $A \to a AAb \mid \epsilon$
Every b is associated with an a in front of it, and anything between these is also associated in the same way so there is always balance.