Let $\mathcal{C}$ be a category. We can construct a category of morphisms $\mathcal{M}$ by letting the objects be morphisms in $\mathcal{C}$ and morphisms be appropriate pairs of morphisms that give a commutative diagram.
Let $f:A \to B$, $g:C \to D$, $h:E \to F$, and $k:G \to H$. A morphism $(r,s) \in \mathrm{Hom}(f,g)$ consists of a map $r:A \to C$ and a map $s:B \to D$, and a morphism $(t,u) \in \mathrm{Hom}(h,k)$ consists of a map $t:E \to G$ and a map $u:F \to H$, all so that the appropriate diagrams commute.
Part of the requirement of a category is that hom-sets be disjoint. Suppose $(r,s)=(t,u)$ for some $(t,u) \in \mathrm{Hom}(h,k)$. Then we must have $r:E \to G$ and $s:F \to H$, so it must be that $A=E$, $C=G$, $B=F$, and $D=H$.
Since the morphisms $r:A \to C$ and $s:B \to D$ form a commutative diagram with $f:A \to B$ and $g:C \to D$, we have the relations $k \circ r=s \circ h$ and $g \circ r=s \circ f$. I'm not sure how to show from here that $r=t$ and $s=u$, which would show that if two hom-sets are not equal then they are disjoint. I see that they must have the same domain and codomain, but I feel like this isn't enough.
How do we show that hom-sets in a morphism category are disjoint?