Well defined:
Let $G$ be a finite group. Suppose that $N$ and $M$ are two subgroups such that $G/N$ and $G/M$ are solvable. Since the product of finitely many solvable groups is itself solvable, we know that $(G/N)\times (G/M)$ is solvable. The map $G\to (G/N)\times (G/M)$ given by $g\mapsto (gN,gM)$ has kernel $N\cap M$, so $G/(N\cap M)$ is isomorphic to a subgroup of a solvable group, hence is itself solvable.
It follows that the intersection $N=\cap N_i$ of finitely many normal subgroups $N_i$ such that $G/N_i$ is solvable is itself a normal subgroup of $G$ such that $G/N$ is solvable. Moreover, $G/G$ is solvable, so every group has normal subgroups such that the quotient is solvable.
Thus, for every finite group $G$, there is a least normal subgroup $N$ of $G$ such that $G/N$ is solvable, namely, $N=\cap\{ M\triangleleft G\mid G/M\text{ is solvable}\}$.
The statement given:
As to what you want to prove: if $G$ is solvable, then every subgroup is solvable, so $U^s=\{e\}$ for all $U\leq G$; hence $U^s=V^s$ always holds. Conversely, since $\{e\}^s=\{e\}$, if $U^s\sim V^s$ for all $U,V\leq G$, then $U^s$ is conjugate to $\{e\}$, hence trivial, for all $U$. In particular, $G^s\sim\{e\}$, so $G^s=\{e\}$, which means that $G^s=\{e\}$. Thus, $G$ is solvable.