I assume that $x$ does not occur free in $\Gamma$.
Yes, it is equivalent to say
- $\Gamma \not\vdash \lnot \exists x A(x)$
- for some $x$, $Γ⊬¬A(x)$
Both of them mean that there is a model of $\Gamma$ and $\exists x A(x)$. Roughly, it means that it is possible to make $\Gamma$ and $\exists x A(x)$ true simultaneously.
Indeed, $\Gamma \not\vdash \lnot \exists x A(x)$ means that $\lnot \exists x A(x)$ is not provable from the hypothesis $\Gamma$, which amounts to say that there is a model of $\Gamma$ and $\exists x A(x)$.
Under the assumption that $x$ is not free in $\Gamma$, $\Gamma \vdash \lnot A(x)$ means that $\lnot A(x)$ is provable from the hypothesis $\Gamma$, for any $x$. It amounts to say that $\Gamma \vdash \forall x \lnot A(x)$.
Therefore, saying that $\Gamma \not\vdash \lnot A(x)$ for some $x$ (i.e. negating that $\Gamma \vdash \lnot A(x)$ for any $x$) means that $\Gamma \not\vdash \forall x \lnot A(x)$, which amounts to say that there is a model of $\Gamma$ and $\lnot \forall x \lnot A(x)$, i.e. there is a model of $\Gamma$ and $\exists x A(x)$.