This is definitely a situation where added generality yields more clarity.
Although in particular contexts only some vector spaces may be of interest, a vector space in general is just the following:
A vector space is a triple $$(\mathcal{V},\mathcal{F},\cdot),$$ where
$\mathcal{F}=(F; +_F,\times_F,0_F,1_F)$ is a field,
$\mathcal{V}=(V; +_V)$ is a group, and
$\cdot$ is a function from $F\times V$ to $V$ satisfying the rules (for all $a,b\in F$ and $u,v\in V$)
$1_F\cdot v=v$
$(a+_Fb)\cdot v=(a\cdot v)+_V(b\cdot v),$
$(a\times_Fb)\cdot v=a\cdot(b\cdot v)$, and
$a\cdot (u+_Vv)=(a\cdot u)+_V(a\cdot v)$.
Any triple of this type is a vector space. In particular, any field can serve as the field of scalars of a vector space, and it's a good exercise to show that a field $\mathcal{F}$ is a vector space over itself in a natural way: take $\mathcal{V}$ to be the underlying additive group of $\mathcal{F}$, and take the scalar multiplication to just be the multiplication of $\mathcal{F}$.
When we're being more specific it should be clear from context what sorts of vector spaces are being considered. Often, for example, we're only interested in the case when $\mathcal{F}=\mathbb{C}$, or $\mathcal{F}=\mathbb{R}$. However, in general there's absolutely no restriction on what fields can serve as the field of scalars of a vector space.
There's a slight slipperiness here, though: what exactly are elements of fields? Sure, any field can be the field of scalars, but what sorts of things can be in fields to begin with? This gets to a "structuralist" aspect of mathematics: we don't care about what the underlying set of a structure - such as a field - actually is, but rather the behavior of that set together with the additional functions/relations/whatever. So anything whatsoever can be an element of the underlying set of a field, and so from a purely mathematical standpoint the question "what is an individual scalar?" isn't really meaningful. Of course, in particular situations we're often only interested in limited examples, and then we can say more - e.g. maybe we only care about subfields of $\mathbb{C}$, in which case we can get away with saying "all vectors are complex numbers," even though strictly speaking that's a bit bunk.