There is a nontrivial necessary condition -- $\omega$ must have constant rank.
The rank of differential form is defined as follows: a $k$-form is said to be decomposable if it can be written locally as a wedge product of $1$-forms. Every $k$-form can be written locally as a sum of decomposable $k$-forms, and the rank of a $k$-form at a point is defined as the minimum number of decomposable terms in any such representation. See this Wikipedia article for more.
A constant-coefficient form obviously has constant rank, so that's a necessary condition for $\omega$ to be expressed as a constant-coefficient form in some coordinates. To see that this condition is stronger than nowhere-vanishing in general, consider the following closed $2$-form on $\mathbb R^4$, with coordinates $(w,x,y,z)$:
$$
\omega = w\, dw\wedge dx + dy \wedge dz.
$$
This is nowhere vanishing, and it has rank $2$ wherever $w\ne 0$, but on the $w=0$ hyperplane it has rank $1$. Thus there are no coordinates in a neighborhood of the origin that will make it constant-coefficient.
For $1$-forms, constant rank just means either identically zero or nowhere-vanishing. Obviously the zero form has a constant-coefficient representation, and as @TedShifrin pointed out in a comment, the Frobenius theorem shows that a nowhere-vanishing closed $1$-form has such a representation in a neighborhood of each point. Thus the constant-rank condition is sufficient for $1$-forms.
For $2$-forms, constant rank is equivalent to the matrix of the form having constant rank in any coordinates. In this case, here's a proof that the constant-rank condition is sufficient: Suppose $\omega$ is a closed $2$-form with constant rank $p$. By the Poincaré lemma, in a neighborhood of each point there is a $1$-form $\theta$ such that $d\theta = \omega$. Then because $d\theta$ has constant rank, the the generalized Darboux theorem implies that there are local coordinates $(x^1,\dots,x^{n-p},y^1,\dots,y^p)$ in which $\theta$ is given by
$$
\theta = x^1\,dy^1 + \dots + x^p\,dy^p,
$$
and therefore $\omega$ has the constant-coefficient expression
$$
\omega = dx^1\wedge dy^1 + \dots + dx^p \wedge dy^p.
$$
I'm not sure about sufficiency for forms of degree higher than $2$, but I suspect it's true in that case as well. I would consult the book Exterior Differential Systems by Bryant et al.