I'm going to share the work I did on this problem---even though I didn't get a positive result. Perhaps you can work with it.
We can write your problem as follows:
$$f(A) = \inf \{ \|B\|_1 \,|\, B=A^{-1} \}$$
Now consider the following modified function:
$$\tilde{f}(A) = \inf \{ \|B\|_1 \,|\, B\succeq A^{-1} \} = \inf\{ \|B\|_1 \,|\, B - A^{-1} \in \mathcal{S}^n_+ \}$$
This function is convex. Here's the proof. First, define the following extended-valued function:
$$g(A,B) = \begin{cases} \|B\|_1 & A \succ 0, ~ B \succeq A^{-1} \\ +\infty & \text{otherwise} \end{cases}$$
If $g(A,B)$ is convex, then so must be $\tilde{f}$, since partial minimizations of convex functions are convex, and $\tilde{f}(A) = \inf_B g(A,B).$ Clearly, $g$ is convex at points in its domain---but we do not know if the domain is convex, yet:
$$\mathop{\textrm{dom}}(g) = \{ (A,B)\in\mathcal{S}^n\times\mathcal{S}^n \,|\, A \succ 0, ~ B \succeq A^{-1} \}
= \left\{ (A,B)\in\mathcal{S}^n\times\mathcal{S}^n \,\middle|\, A \succ 0, ~ \begin{bmatrix} B & I \\ I & A \end{bmatrix} \succeq 0 \right\}.$$
This is a convex set, being the intersection of some linear matrix inequalities on $(A,B)$. Therefore, $g$ is convex, and so is $\tilde{f}$.
Now: is $f\equiv \tilde{f}$? It is true for other convex functions on $B$, such as the trace and the determinant: and indeed, both $\mathop{\textrm{Tr}}(A^{-1})$ and $\mathop{\textrm{det}}(A^{-1})$ are convex. But is it true for $\|A^{-1}\|_1$? Before I tried to prove this, I wrote some MATLAB code using CVX, a toolbox I wrote for convex optimization. Here's the code:
function test_norm1inv( A )
n = size(A,1);
cvx_begin quiet
variable B(n,n) symmetric
minimize(sum(sum(abs(B))));
[B,eye(n);eye(n),A] == semidefinite(2*n)
cvx_end
fprintf( 'CVX result: %g\n', cvx_optval )
fprintf( 'Analytic result: %g\n', sum(sum(abs(inv(A)))) );
Here's some example output:
>> A = randn(10,10); test_norm1inv( A*A' )
CVX result: 44998.8
Analytic result: 45000.3
>> A = randn(10,10); test_norm1inv( A*A' )
CVX result: 686.876
Analytic result: 686.889
>> A = randn(10,10); test_norm1inv( A*A' )
CVX result: 87.0088
Analytic result: 99.938
>> A = randn(10,10); test_norm1inv( A*A' )
CVX result: 82.3252
Analytic result: 96.8455
BZZT. I'm glad I didn't spend any time trying to prove the positive---it is clear that $\tilde{f}\not\equiv f$. I've manually confirmed that the matrix $B$ produced by CVX does indeed satisfy $B\succeq A^{-1}$, and that $\|B\|_1<\|A^{-1}\|_1$. Indeed, the values of $B$ produced by this approach look quite different from $A^{-1}$.
Now I have to say that this shakes any confidence I might have had that your original function, $f$, is convex. That said, I also wrote some simple code to perform convexity tests on pairs of randomly generated PSD matrices, and it failed to find a counterexample. If I think of anything more, I will edit my answer.