A Riemannian manifold $M$ is said to be homogeneous if the group of isometries $Isom(M)$ acts transitively on $M$.
A Riemannian manifold is said to be symmetric if it is connected, homogenuous, and in addition, there exists a point $p\in M$ and an involution $\phi\in Isom(M)$ such that $p$ is an isolated fixed point of $\phi$ (that is, there exists an open neighborhood $V$ of $p$ where $p$ is the only fixed point of $\phi$ among all elements of $V$)
It thus follows that even though a homogeneous spaces are very nice and "symmetric" in the sense that all points look geometrically the same, they are nevertheless not considered to be a symmetric space by the definition above (at least a priori).
The inevitable question is thus:
Is there a relatively simple example of a connected and homogeneous space which is not a symmetric space?