No, there are plenty of matrices with repeated eigenvalues which are diagonalizable. The easiest example is
$$
A=\begin{bmatrix}1&0\\0&1\end{bmatrix}.
$$
The identity matrix has $1$ as a double eigenvalue and is (already) diagonal. If you want to write this in diagonalized form, you can write
$$
A=I^{-1}AI=I^{-1}II
$$
since $A$ is a diagonal matrix.
In general, $2\times 2$ matrices with repeated eigenvalue $\lambda$ are diagonalizable if and only if the eigenspace corresponding to $\lambda$ is two dimensional. In other words, if
$$
A-\lambda I=\begin{bmatrix}a-\lambda&b\\c&d-\lambda\end{bmatrix}
$$
has a two-dimensional null space. Using the rank-nullity theorem, we get that this happens exactly when the matrix has $0$ pivots. If $A-\lambda I$ has any nonzero entries, then it will have a pivot. Therefore, a $2\times 2$ matrix with repeated eigenvalues is diagonalizable if and only if it is $\lambda I$.
If $B$ is an $n\times n$ matrix, all of whose eigenvalues are $\lambda$, a similar result holds. A sneakier way to prove this is that if $B$ is diagonalizable, then
$$
B=P^{-1}(\lambda I)P=\lambda P^{-1}IP=\lambda I,
$$
where P is an invertible (basis changing) matrix.
Therefore, the only $n\times n$ matrices with all eigenvalues the same and are diagonalizable are multiples of the identity.
If only some of $B$'s eigenvalues have multiplicity, then the situation becomes more complicated and you really need to compute the dimensions of all the eigenspaces.
As the other posters comment, there are diagonal matrices which are not multiples of the identity, for example
$$
\begin{bmatrix}1&0\\0&2\end{bmatrix}
$$
and if all the eigenvalues of a matrix are distinct, then the matrix is automatically diagonalizable, but there are plenty of cases where a matrix is diagonalizable, but has repeated eigenvalues.