New Solution
Have just found a proof which does not require the prior knowledge of the result of the sum of integers.
$$\begin{align}
\sum_{i=1}^n i^2&=\sum_{i=1}^n\sum_{j=1}^i(2j-1)&& ...(1)\\
\sum_{i=1}^n i^2&=\sum_{i=1}^n\sum_{j=1}^i 2(n-i)+1&& ...(2)\\
\sum_{i=1}^n i^2&=\sum_{i=1}^n\sum_{j=1}^i 2(i-j)+1&& ...(3)\\
(1)+(2)+(3):\\
3\sum_{i=1}^n i^2
&=\sum_{i=1}^n\sum_{j=1}^i (2j-1)+2(n-1)+1+2(i-j)+1\\
&=\sum_{i=1}^n\sum_{j=1}^i (2n+1)\\
&=(2n+1)\sum_{i=1}^n i\\
\sum_{i=1}^n i^2&=\frac{2n+1}3\sum_{i=1}^n i\qquad\blacksquare
\end{align}$$
This proof is a transcription of the diagrammatic proof of the same as shown on the wikipedia page here.
See also the nice diagrams in this solution here.
Earlier post shown below
This is too long for a comment so it's being posted in the solution section.
A synthetic and rather cumbersome approach might be as follows:
$$\begin{align}
(2m+1)\sum_{r=1}^mr-(2m-1)\sum_{r=1}^{m-1}r
&=(2m+1)\frac {m(m+1)}2-(2m-1)\frac{m(m-1)}2\\
&=\frac m2\left[(2m+1)(m+1)-(2m-1)(m-1)\right]\\
&=3m^2\end{align}$$
Summing $m$ from $1$ to $n$ and telescoping LHS gives
$$(2n+1)\sum_{r=1}^nr=3\sum_{m=1}^nm^2\color{lightgray}{=3\sum_{r=1}^n r^2}\\
\sum_{r=1}^nr^2=\frac {2n+1}3\sum_{r=1}^nr\qquad\blacksquare$$