Why aren't probability spaces just defined as $(\Omega, p)$ pairs with $\Omega$ as the sample space, $\sum_{\omega \in \Omega}p(\omega) = 1$, and for a subset $A \subseteq \Omega$, $\Pr(A) := \sum_{\omega \in A}p(\omega)$?
Said another way, why aren't all $(\Omega, \mathcal{A}, p)$ probability spaces of the form $(\Omega, \mathcal{P}(\Omega), p)$? What do we gain by giving ourselves the freedom to exclude certain subsets of $\Omega$ from $\mathcal{A}$ ?