There are indeed generalization of the angle sums relations to spherical $d$-polytopes.
However, the generalization I know doesn't involve the volume of the polytope for odd $d$.
- Let $P$ any spherical/euclidean/hyperbolic $d$-polytope.
- Let $F_j$ be the collection of $j$-faces of $P$ for $0 \le j \le d$.
- For each face $f$ of $P$, take a interior point $p$ of $f$ and define
$$\alpha_f(P) = \lim_{\epsilon \to 0}\frac{\verb/Vol/(P \cap B_p(\epsilon) )}{\verb/Vol/(B_p(\epsilon))}$$
- Define a bunch of coefficients $\alpha_{-1}(P), \alpha_{0}(P), \ldots, \alpha_{d}(P)$ by:
$$\alpha_{-1}(P) = \frac{\verb/Vol/(P)}{\verb/Vol/(B(1))}
,\quad \alpha_{j}(P) = \sum_{f\in F_j} \alpha_{f}(P)\quad\text{ for } 0 \le j \le d
$$
where $B(1)$ is the whole sphere when $P$ is spherical and any unit $d$-ball (I believe) when $P$ is hyperbolic.
We have
Generalized Gram relations (Grünbaum, Sommerville, Heckman)
$$
\sum_{j = 0}^d (-1)^j \alpha_j(P) = \varepsilon^{d/2}(1 + (-1)^d)\alpha_{-1}(P)
\quad\text{ where }\quad
\varepsilon =
\begin{cases}
\;1, & P \quad\text{ spherical }\\
\;0, & P \quad\text{ euclidean }\\
-1, & P \quad\text{ hyperbolic }
\end{cases}$$
For the special case of tetrahedron at $d = 3$, independent of whether it is spherical/euclidean/hyperbolic, above formula reduces to
$$\sum_{v \in V} \frac{\Omega_v}{4\pi} - \sum_{e \in E} \frac{\theta_e}{2\pi} +\frac{|F|}{2} - 1 = 0$$
where
$V, E, F$ are the set of vertices/edges/facets of tetrahedron,
$\Omega_v$ is the solid angle at vertex $v$ and $\theta_e$ is the dihedral angle at edge $e$.
As one can see, this formula doesn't involve the volume for odd number $d = 3$.
I don't really know this stuff, above formula is extracted from
the paper Angle sums on polytopes and polytopal complexes by Kristin A. Camenga. Look at $\S 4.2$ there for a more accurate description of the relations and references there for more details.